@riskchurch13
active 4 hours, 37 minutes ago
The reactivity of the geminal frustrated Lewis pair (FLP) (F5 C2 )3 SnCH2 P(tBu)2 (1) was explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH, H3 CC(O)CH=CH2 , Ph[C(O)]2 Ph, PhN=NPh and Me3 SiCHN2 ), featuring polar or non-polar multiple bonds and/or represent α,β-unsaturated systems. While most adducts are f […] View