To sum up, GONRs is a potential agent as a novel antioxidant and skin-whitening cosmetology material. Copyright © 2020 American Chemical Society.An inimitable urea-based multichannel chemosensor, DTPH [1,5-bis-(2,6-dichloro-4-(trifluoromethyl)phenyl)carbonohydrazide], was examined to be highly proficient to recognize CN- based on the H-bonding interaction between sensor -NH moiety and CN- in aqueous medium with explicit selectivity. Selleck BMS-1166 In the absorption spectral titration of DTPH, a new peak at higher wavelength was emerged in titrimetric analytical studies of CN- with the zero-order reaction kinetics affirming the substantial sensor-analyte interaction. The isothermal titration calorimetry (ITC) experiment further affirmed that the sensing process was highly spontaneous with the Gibbs free energy of -26 × 104 cal/mol. The binding approach between DTPH and CN- was also validated by more than a few experimental studies by means of several spectroscopic tools along with the theoretical calculations. A very low detection limit of the chemosensor toward CN- (0.15 ppm) further instigated to design an RGB-based sensory device based on the colorimetric upshots of the chemosensor in order to develop a distinct perception regarding the presence of innocuous or precarious level of the CN- in a contaminated solution. Moreover, the reversibility of the sensor in the presence of CN- and Hg2+ originated a logic gate mimic ensemble. Additionally, the real-field along with the in vitro CN- detection efficiency of the photostable DTPH was also accomplished by using various biological specimens. Copyright © 2020 American Chemical Society.An environmental strategy for developing sustainable materials presents an attractive prospect for wastewater remediation. Herein, a facile, green, and economical strategy is proposed to fabricate magnetic composite nanoparticles (NPs) toward cationic dye adsorption and selective degradation. To prepare the composite TiO2-PEI-TA@Fe3O4 NPs, tannic acid (TA) and polyethyleneimine (PEI) were first used to decorate Fe3O4 NPs at aqueous solution, and then TiO2 NPs were anchored onto the surfaces of Fe3O4 NPs based on the catecholamine chemistry. The chemical composition and microstructure of the obtained NPs were systematically characterized. The NPs not only exhibited adsorption ability for the cationic dye of methylene blue (MB) but also responded to ultraviolet light to selectively degrade the adsorbed MB, and the removal (adsorption and/or degradation) ratio for MB could reach 95%. In addition, cyclic experiments showed that the removal ratio of the composite NPs for MB could still be maintained more than 85% even after five cycles. Given by the above-mentioned advantages, such a green and facile strategy for combining the adsorption and degradation methods to construct magnetic nanocomposites exhibits potential applications in cationic dye selective removal and sustainable wastewater remediation. Copyright © 2020 American Chemical Society.Biobutanol is a promising alternative fuel for spark-ignition engines. Exhaust gas recirculation (EGR) and air dilution were evaluated on a TGDI engine fueled with butanol-gasoline (B20) in view of engine operation, efficiency, gaseous emissions, and PM emissions. For the B20 engine, EGR affected combustion more strongly than excess air dilution; the brake thermal efficiency (BTE) under excess air dilution was much higher than that with EGR. The oxygen concentration in the cylinder was also markedly reduced with EGR relative to air dilution, as the partial fresh charge was substituted with nonreactive gas. A reduced oxygen concentration contributed to differences in combustion between excess air dilution and EGR. Higher BTE was observed during combined EGR and excess air dilution operation, though it was slightly lower than that under excess air dilution alone. NO x was also markedly reduced by the combination of EGR and excess air dilution, but was slightly higher than that with EGR alone. Under combined dilution conditions, the particle number (PN) emissions from the B20 engine were reduced significantly, particle sizes decreased, and the nucleate PN significantly decreased. Copyright © 2020 American Chemical Society.Clays, hydrous aluminous phyllosilicates, have a significant impact on the interpretation of physical measurements and properties of porous media. In particular, the presence of paramagnetic and/or ferromagnetic ions like iron, nickel, and magnesium in clays can complicate the analysis of nuclear magnetic resonance (NMR) data for porous media characterization. This is due to the internal magnetic field gradient induced by the clay minerals. In this study, we aim to investigate the impact of clay content on spin-spin relaxation time (T 2), which is strongly influenced by the pore surface chemistry. Seven rock core plugs, characterized with variable clay content, were used for this purpose. The clay mineralogy and volume were determined by means of quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN). The T 2 relaxation time was measured using a Carr-Purcell-Meiboom-Gill (CPMG) sequence with variable echo spacing (T E). The maximum percentage difference in dominant T 2 values (MRDT 2) bn internal magnetic gradients and T 2 signal may result in considerable underestimation of the actual pore size distribution. Copyright © 2020 American Chemical Society.Nanosized mesoporous CuMgAl ternary oxide catalysts were prepared by thermal decomposition of CuMgAl-layered double hydroxides at 500 °C with nominal Cu/Mg/Al ratios of 111 (Cu-LDH-I), 1.50.51 (Cu-LDH-II), and 201 (Cu-LDH-III). The synthesized catalysts were characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), Fourier transform infrared (FTIR) spectroscopy, CO2-TPD, and N2 physisorption analysis techniques. The catalytic activity of the synthesized materials was investigated for the Henry reaction between nitromethane and numerous aldehyde derivatives under ultrasonic irradiation. The three CuMgAl ternary oxide catalysts exhibited a high catalytic activity, forming nitro alcohol products with 100% atom economy. The CuMgAl-I catalyst derived from Cu-LDH-I offered high turnover frequencies (TOFs in the synthesis of all of the nitro alcohols in shorter reaction times).